Denatonium Benzoate

Bitrex, Denatonium Salt, Benzyldiethyl [(2,6-xylylcarbamoyl) methyl] ammonium benzoate.

CAS
3734-33-6
EC
223-095-2
Sectors
Automotive, Home Care & Industrial Cleaning

Denatonium Benzoate (CAS 3734-33-6) is an ammonium benzoate salt supplied as a white crystalline solid that ranks as the most bitter substance known, effective at concentrations as low as 10 parts per million, and is used mainly as an aversive agent in alcohol denaturation, automotive fluids and household products. This Technical Grade solid is essential for denaturing alcohols and preventing accidental ingestion of hazardous household products. Its high stability across various temperatures and pH levels makes it an ideal additive for diverse liquid formulations. In the automotive sector, it is a mandatory additive for antifreeze and coolants to protect wildlife and children. The compound’s odorless property ensures it does not interfere with the primary fragrance or function of the end product.

Typical Properties

Molecular formulaC21H29N2O.C7H5O2
Molecular weight446.58 g/mol
Appearancewhite crystals
FormSolid
ColorWhite to Off-White
Odorat 100.00?%. bland
Melting point168 °C
Water solubility42.555g/L at 25°C
Flash point100°C
GHS signal wordDanger · Corrosive, Irritant / harmful
HS code29242995
Grades availableTechnical Grade

Typical literature values for identification; lot-specific results are stated on the certificate of analysis (COA) and the safety data sheet (SDS) that accompany every delivery.

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Denatonium Benzoate

Applications
  • Alcohol Denaturation: Added to ethanol and isopropyl alcohol to make them unfit for human consumption, often for tax or safety purposes.
  • Automotive Fluids: Integrated into ethylene glycol-based antifreeze and windshield washer fluids as a safety bittering agent.
  • Household Products: Used in liquid detergents, disinfectants, and garden chemicals to discourage accidental swallowing.
Safety & Risks

Classified as Acute Toxic (Oral) and a Skin/Eye Irritant. While used in small doses, the pure form requires Dust Masks (N95), Safety Glasses, and Protective Gloves during blending.

Packaging

Commonly supplied in 1 kg Tins, 5 kg Foil Bags, and 25 kg Fiber Drums for large-scale industrial compounding.