Methyl Ethyl Ketoxime
MEKO, 2-Butanone oxime.
- CAS
- 96-29-7
- EC
- 202-496-6
- Sectors
- Coatings, Adhesives, Sealants & Elastomers
Methyl Ethyl Ketoxime (CAS 96-29-7), also known as MEKO or 2-butanone oxime, is an oxime supplied as a clear, colorless liquid with a characteristic odor, typically offered at >99% purity, and used as an anti-skinning agent for alkyd paints and varnishes and as an isocyanate blocking agent in polyurethane coatings. It works by preventing the oxidative polymerization of drying oils at the surface of the liquid in the container. This Technical Grade chemical is essential for maintaining the shelf life of alkyd-based paints and varnishes. Its high volatility ensures it evaporates quickly after application, allowing the coating to cure naturally.
Typical Properties
| Molecular formula | C4H9NO |
|---|---|
| Molecular weight | 87.12 g/mol |
| Appearance | colourless liquid |
| Form | Liquid |
| Color | Clear colorless to pale yellow |
| Odor | Musty odor |
| Melting point | -29.5 °C |
| Boiling point | 149-151 °C |
| Density | 0.9232 g/cm³ @ Temp: 80 °C |
| Water solubility | 114 g/L (20 °C) |
| Flash point | 140 °F |
| GHS signal word | Danger · Corrosive, Acute toxicity, Irritant / harmful, Health hazard |
| HS code | 29280090 |
| Grades available | Technical Grade |
Typical literature values for identification; lot-specific results are stated on the certificate of analysis (COA) and the safety data sheet (SDS) that accompany every delivery.
Methyl Ethyl Ketoxime
Applications
• Paint & Coatings: Prevents the formation of a "skin" on the surface of oil-based paints during storage.
• Polyurethane Systems: Used to block isocyanate groups in one-component (1K) heat-cured systems.
• Silicone Sealants: Acts as a cross-linking agent (oxime-cure) for RTV silicone formulations.
Safety & Risks
Classified as Carcinogenic Category 1B and Serious Eye Damage Category 1. Handle under strict exhaust ventilation using Viton gloves and full-face respirators.
Packaging
190 kg steel drums or 950 kg IBC tanks.