Methyl Ethyl Ketoxime

MEKO, 2-Butanone oxime.

CAS
96-29-7
EC
202-496-6
Sectors
Coatings, Adhesives, Sealants & Elastomers

Methyl Ethyl Ketoxime (CAS 96-29-7), also known as MEKO or 2-butanone oxime, is an oxime supplied as a clear, colorless liquid with a characteristic odor, typically offered at >99% purity, and used as an anti-skinning agent for alkyd paints and varnishes and as an isocyanate blocking agent in polyurethane coatings. It works by preventing the oxidative polymerization of drying oils at the surface of the liquid in the container. This Technical Grade chemical is essential for maintaining the shelf life of alkyd-based paints and varnishes. Its high volatility ensures it evaporates quickly after application, allowing the coating to cure naturally.

Typical Properties

Molecular formulaC4H9NO
Molecular weight87.12 g/mol
Appearancecolourless liquid
FormLiquid
ColorClear colorless to pale yellow
OdorMusty odor
Melting point-29.5 °C
Boiling point149-151 °C
Density0.9232 g/cm³ @ Temp: 80 °C
Water solubility114 g/L (20 °C)
Flash point140 °F
GHS signal wordDanger · Corrosive, Acute toxicity, Irritant / harmful, Health hazard
HS code29280090
Grades availableTechnical Grade

Typical literature values for identification; lot-specific results are stated on the certificate of analysis (COA) and the safety data sheet (SDS) that accompany every delivery.

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Methyl Ethyl Ketoxime

Applications

• Paint & Coatings: Prevents the formation of a "skin" on the surface of oil-based paints during storage.

• Polyurethane Systems: Used to block isocyanate groups in one-component (1K) heat-cured systems.

• Silicone Sealants: Acts as a cross-linking agent (oxime-cure) for RTV silicone formulations.

Safety & Risks

Classified as Carcinogenic Category 1B and Serious Eye Damage Category 1. Handle under strict exhaust ventilation using Viton gloves and full-face respirators.

Packaging

190 kg steel drums or 950 kg IBC tanks.