Methyl Formate

Methyl Methanoate

CAS
107-31-3
EC
203-481-7
Sectors
Plastics & Polymers, Building & Construction

Methyl Formate (CAS 107-31-3) is a methyl ester of formic acid that appears as a clear colorless liquid with a pleasant ether-like odor; it serves as a solvent and blowing agent in polyurethane foam and insulation production and as an intermediate in formamide and dimethylformamide (DMF) synthesis. It is an ester formed from methanol and formic acid, notable for its high vapor pressure and rapid evaporation rate.

Typical Properties

Molecular formulaC2H4O2
Molecular weight60.05 g/mol
AppearanceMethyl formate is a colorless liquid with a pleasant odor.
FormLiquid
ColorClear colorless
OdorPleasant; agreeable.
Melting point-99.8 °C
Boiling point31.5 °C
Density0.987 g/cm³ @ Temp: 15 °C
Water solubility300 G/L (20 °C)
Flash point−16 °F
pH4-5 (200g/l, H2O, 20°C)
GHS signal wordDanger · Flammable, Acute toxicity, Irritant / harmful, Health hazard
Grades availableTechnical Grade

Typical literature values for identification; lot-specific results are stated on the certificate of analysis (COA) and the safety data sheet (SDS) that accompany every delivery.

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Methyl Formate

Applications

Used as a solvent, blowing agent, and intermediate in chemical synthesis. In polyurethane foam and insulation production, it serves as an eco-friendly blowing agent replacing CFCs. Industrially, it is employed in formamide and dimethylformamide (DMF) synthesis.

Safety & Risks

Highly flammable and mildly toxic by inhalation; avoid ignition sources and ensure adequate ventilation.

Packaging

Supplied in 180–200 L steel drums or 1,000 L IBC tanks. Store cool, dry, and tightly sealed away from acids and oxidizers.