Sodium Monochloroacetate

SMCA, Sodium Chloroacetate, Monoxone.

CAS
3926-62-3
EC
223-498-3
Sectors
Personal Care & Cosmetics, Agriculture

Sodium Monochloroacetate (CAS 3926-62-3) is the sodium salt of chloroacetic acid, a white crystalline powder supplied in Technical Grade, and it acts as an alkylating agent that introduces the carboxymethyl group into organic molecules, polymers and natural fibers for CMC, surfactant and agrochemical production. The chemical is a cornerstone for the production of Carboxymethyl Cellulose (CMC) , a vital thickener used in food, pharmaceuticals, and oil drilling. Its high water solubility and reactivity make it an efficient reagent for synthesizing a wide array of surfactants and amphoteric compounds. In the agrochemical sector, SMCA is a key intermediate for various herbicides and plant growth regulators. Its consistent chemical profile ensures high-yield reactions in industrial processes, while its stable salt form offers safer handling than the parent monochloroacetic acid.

Typical Properties

Molecular formulaC2H3ClO2.Na
Molecular weight116.48 g/mol
Appearancewhite crystalline powder
FormCrystalline Powder
ColorWhite
Melting point150-200 °C (decomp)
Density1.87[at 20°C]
Water solubility440 g/L (20 °C)
Flash point270°C
pH4.5-9.0 (50g/l, H2O, 20°C)
GHS signal wordDanger · Acute toxicity, Irritant / harmful, Health hazard, Environmental hazard
HS code29154000
Grades availableTechnical Grade

Typical literature values for identification; lot-specific results are stated on the certificate of analysis (COA) and the safety data sheet (SDS) that accompany every delivery.

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Sodium Monochloroacetate

Applications
  • CMC Manufacture: Reacts with cellulose to produce Carboxymethyl Cellulose, used as a rheology modifier and stabilizer in multiple industries.
  • Surfactant Synthesis: Essential for producing betaines and other amphoteric surfactants used in mild shampoos and personal care products.
  • Agrochemicals: Serves as an intermediate for the production of phenoxy-herbicides and other specialized crop protection chemicals.
Safety & Risks

Classified as Toxic if Swallowed and Skin/Eye Irritant. Highly toxic to aquatic life; handle with Gloves, Goggles, and Dust Masks in well-ventilated areas.

Packaging

25 kg PE-lined Woven Bags and 1000 kg Big Bags.