Sodium Bifluoride

Sodium Hydrogen Fluoride

CAS
1333-83-1
EC
215-608-3
Sectors
Lubricants & Metalworking, Agriculture

Sodium Bifluoride (CAS 1333-83-1) is sodium hydrogen difluoride, a white crystalline solid supplied as pellets that dissolves in water to release hydrofluoric acid for acidic fluoride applications, and it is used in metal cleaning, aluminum etching, glass frosting and pesticide formulations. Produced from sodium fluoride and HF, it follows industrial standards from industry fluorides and ChemSpider structures.

Sodium Bifluoride reaches metalworking and agricultural customers through SoleChem in Technical Grade. The material ships sealed in 25 kg plastic pails with hazard labels for safe transit.

SoleChem stocks Technical Grade Sodium Bifluoride for lubricants and metalworking operations as well as for agricultural formulators, and holds ISO 9001:2015 certification for these supply activities. A certificate of analysis (COA) and safety data sheet (SDS) accompany every delivery, and SoleChem provides deliveries to more than 40 countries. Request a bulk quote with your target quantity, packaging preference and delivery schedule.

Typical Properties

Molecular formulaF2H.Na
Molecular weight61.99 g/mol
AppearanceWhite, crystalline powder.Sol- uble in water; decomposes on heating.
Formpellets
Colorwhite hexagonal, hexane crystals, crystalline
Melting point>68 °C (dec.)
Boiling point270°C[at 101 325 Pa]
Density2.08 g/cm³
Water solubilityg/100g solution in H2O: 3.7 (20°C), 16.4 (80°C) [KIR78]
GHS signal wordDanger · Corrosive, Acute toxicity, Health hazard
HS code2826199090
Grades availableTechnical Grade

Typical literature values for identification; lot-specific results are stated on the certificate of analysis (COA) and the safety data sheet (SDS) that accompany every delivery.

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Applications by Industry

  • Lubricants & Metalworking

    Sodium Bifluoride supports metalworking operations as a cleaning and etching agent for aluminum surfaces and as a flux component in electroplating baths.

  • Agriculture

    Sodium Bifluoride serves agricultural formulators as an active ingredient in pesticide products, supporting crop protection formulations.

Sodium Bifluoride

Applications

Used in metal cleaning for aluminum etching; in laundry sours for pH lowering; in glass frosting pastes; in electroplating for flux; and in pesticides as active ingredients.

Safety & Risks

Highly toxic causing fluoride burns and hypocalcemia; inhalation leads to pulmonary edema. Provide calcium gluconate antidote; full PPE mandatory per GHS corrosive classifications.

Packaging

Sealed in 25 kg plastic pails with hazard labels for safe transit. Secure in bifluoride isolated cabinets with spill kits.