Ammonium Bifluoride

Ammonium Acid Fluoride

CAS
1341-49-7
EC
215-676-4
Sectors
Mining & Metals, Building & Construction, Oil, Gas & Energy

Ammonium bifluoride (NH₄HF₂) is a crystalline, acidic fluoride salt used where controlled release of hydrogen fluoride is required. Its strong reactivity toward oxides and silicates makes it indispensable in surface finishing industries.

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Ammonium Bifluoride

Applications

Commonly applied in stainless-steel pickling, glass frosting, and masonry cleaning formulations. In the oilfield sector, it serves as an acidizing additive that promotes dissolution of siliceous scales. It is also an intermediate in fluorine compound synthesis.

Safety & Risks

Highly corrosive and toxic; contact causes severe burns and systemic fluoride poisoning. Generates HF vapors in moisture. Handle only with HF-resistant equipment and PPE, including gloves, face shield, and apron; calcium gluconate gel must be available on-site.

Packaging

Supplied in acid-resistant HDPE drums or plastic-lined steel containers. Store in ventilated, cool areas isolated from bases and oxidizers. Keep containers tightly closed and dry.