Ammonium Bifluoride

Ammonium Acid Fluoride

CAS
1341-49-7
EC
215-676-4
Sectors
Mining & Metals, Building & Construction, Oil, Gas & Energy

Ammonium Bifluoride (CAS 1341-49-7) is a crystalline acidic fluoride salt that appears as white scales or flakes and is used where controlled release of hydrogen fluoride is required, serving stainless-steel pickling, glass frosting, masonry cleaning and oilfield acidizing. Its strong reactivity toward oxides and silicates makes it indispensable in surface finishing industries.

Ammonium Bifluoride ships from SoleChem stock in Technical Grade and is supplied in acid-resistant HDPE drums or plastic-lined steel containers for industrial buyers. SoleChem serves customers in Mining & Metals, Building & Construction and Oil, Gas & Energy, and its deliveries reach more than 40 countries.

SoleChem holds ISO 9001:2015 certification covering the supply of this Technical Grade material from stock. A certificate of analysis (COA) and safety data sheet (SDS) accompany every delivery. Tell us your required volume, preferred packaging and target delivery schedule to request a bulk quote.

Typical Properties

Molecular formulaF2H.H4N
Molecular weight57.04 g/mol
Appearancewhite scales or flakes
FormSolid
ColorWhite
Odoracidic odor
Melting point125.6 °C
Boiling point240 °C (decomp)
Density1.50 g/cm³
Water solubility630 g/L (20 °C)
Flash point238°C
pH2 (5.7g/l, H2O, 20°C)
GHS signal wordDanger · Corrosive, Acute toxicity, Irritant / harmful, Health hazard
HS code28261900
Grades availableTechnical Grade

Typical literature values for identification; lot-specific results are stated on the certificate of analysis (COA) and the safety data sheet (SDS) that accompany every delivery.

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Applications by Industry

  • Mining & Metals

    Ammonium Bifluoride serves metal processors as a pickling agent for stainless steel, supporting the removal of oxide scale from metal surfaces.

  • Building & Construction

    Ammonium Bifluoride is used in building and construction work for masonry cleaning formulations and glass frosting, where controlled fluoride release is required.

  • Oil, Gas & Energy

    Ammonium Bifluoride acts as an acidizing additive in oilfield operations, promoting the dissolution of siliceous scales that restrict flow.

Ammonium Bifluoride

Applications

Commonly applied in stainless-steel pickling, glass frosting, and masonry cleaning formulations. In the oilfield sector, it serves as an acidizing additive that promotes dissolution of siliceous scales. It is also an intermediate in fluorine compound synthesis.

Safety & Risks

Highly corrosive and toxic; contact causes severe burns and systemic fluoride poisoning. Generates HF vapors in moisture. Handle only with HF-resistant equipment and PPE, including gloves, face shield, and apron; calcium gluconate gel must be available on-site.

Packaging

Supplied in acid-resistant HDPE drums or plastic-lined steel containers. Store in ventilated, cool areas isolated from bases and oxidizers. Keep containers tightly closed and dry.