Synthetic Cryolite

Sodium Hexafluoroaluminate

CAS
13775-53-6
EC
237-410-6
Sectors
Mining & Metals, Agriculture

Synthetic Cryolite (CAS 13775-53-6), also known as sodium hexafluoroaluminate, is a white crystalline salt of the Salts & Minerals class that fluxes at 1000°C to dissolve alumina in the Hall-Héroult process and is used in aluminum smelting electrolytes, abrasive wheels, insecticides, vitreous enamels and fireworks.

SoleChem, an ISO 9001:2015 certified chemical supplier based in Türkiye, delivers Synthetic Cryolite (CAS 13775-53-6) to customers in more than 40 countries.

Typical Properties

Molecular formulaAlF6.3Na
Molecular weight209.94 g/mol
FormCrystals
ColorWhite
Melting point1009 °C
Density1.941 g/cm³
Water solubilitySparingly soluble in water(0.602 g/L at 20°C).
GHS signal wordDanger · Irritant / harmful, Health hazard, Environmental hazard
Grades availableTechnical Grade

Typical literature values for identification; lot-specific results are stated on the certificate of analysis (COA) and the safety data sheet (SDS) that accompany every delivery.

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Applications by Industry

  • Mining & Metals

    Synthetic Cryolite serves aluminum smelters as a fluxing agent in Hall-Héroult electrolytes, where it dissolves alumina at 1000°C, and is also used in abrasive wheels for bonding.

  • Agriculture

    Synthetic Cryolite acts as a stomach poison in insecticide formulations applied to protect crops from chewing pests.

Synthetic Cryolite

Applications

In aluminum smelting electrolytes; in abrasive wheels for bonding; in insecticides as stomach poisons; in vitreous enamels; and in fireworks for green flames.

Safety & Risks

Fluoride ions release toxic skeletal fluorosis chronic. Aquatic persistent; use HF-resistant PPE and calcium gluconate for exposures.

Packaging

Packaged in 50 kg fiber-reinforced plastic barrels. Store in fluoride-safe dry zones.