Hypophosphorous Acid

HPA, Phosphinic Acid

CAS
6303-21-5
EC
228-601-5
Sectors
Electronics & Solar PV, Pharma & Healthcare, Textiles, Leather & Paper

Hypophosphorous Acid (CAS 6303-21-5), also known as phosphinic acid, is an inorganic acid that occurs as a colorless, oily liquid or hygroscopic crystals, is stable in solution and soluble in water and alcohols, and acts as a powerful reducing agent in electroless nickel plating, pharmaceutical synthesis and textile bleaching.

Typical Properties

Molecular formulaH3O2P
Molecular weight66 g/mol
Appearancecolourless liquid
Formhygroscopic crystals or colorless oily liquid
ColorColorless
Melting point26.5 °C
Boiling point108 °C (759.8513 mmHg)
Density1.479 g/cm³ @ Temp: 20 °C
Water solubilitySOLUBLE
pHpKa1= 1.00(25°C)
GHS signal wordDanger · Corrosive
HS code28111990
Grades availableTechnical Grade

Typical literature values for identification; lot-specific results are stated on the certificate of analysis (COA) and the safety data sheet (SDS) that accompany every delivery.

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Hypophosphorous Acid

Applications

Used as a reducing agent in electroless nickel plating, polymerization inhibitors, and pharmaceutical synthesis. Also employed in the production of phosphinate salts and as a bleaching agent in textiles.

Safety & Risks

Corrosive and may release phosphine gas upon heating or contact with oxidizers. Use acid-resistant protective equipment and store under proper ventilation.

Packaging

Supplied in 25–250 kg HDPE drums or IBC tanks. Store cool, dry, and away from strong oxidizing agents and metals.