Sodium Methyl Mercaptide

SMM, Sodium Methanethiolate, Sodium Methyl Thiolate

CAS
5188-07-8
EC
225-969-9
Sectors
Agriculture, Pharma & Healthcare, Plastics & Polymers

Sodium Methyl Mercaptide (CAS 5188-07-8) is a highly reactive organosulfur compound supplied as a 20-25% aqueous solution or as a moisture-sensitive solid, and it acts as a powerful nucleophile that introduces methylthio groups into organic molecules, serving as a key intermediate in agrochemical, pharmaceutical and polymer production. It is a powerful nucleophile, essential for the introduction of methylthio groups into various organic molecules during complex synthesis.

This chemical is a critical intermediate in the large-scale production of Agrochemicals, specifically for the synthesis of systemic pesticides and herbicides. Its high reactivity ensures efficient conversion rates in industrial reactors, supporting the manufacturing of high-demand crop protection products.

The substance is characterized by its strong odor and extreme sensitivity to air and moisture, requiring handling under nitrogen blankets. It provides a specialized sulfur source that is vital for the pharmaceutical industry in the synthesis of methionine and other sulfur-containing active ingredients.

Typical Properties

Molecular formulaCH4S.Na
Molecular weight70.09 g/mol
AppearanceVery faint yellowish red clear liquid
FormPowder
ColorWhite to off-white
Density1.12[at 20°C]
Water solubilitysoluble
Flash point27°C
GHS signal wordDanger · Flammable, Corrosive, Acute toxicity
HS code29309090
Grades availableTechnical Grade

Typical literature values for identification; lot-specific results are stated on the certificate of analysis (COA) and the safety data sheet (SDS) that accompany every delivery.

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Sodium Methyl Mercaptide

Applications
  • Pesticide Production: Acts as a key building block for the synthesis of herbicides like Metribuzin and insecticides like Methomyl.
  • Pharmaceutical Intermediate: Used in the synthesis of essential amino acids and various therapeutic agents requiring methylthio functional groups.
  • Polymer Industry: Functions as a chain transfer agent and modifier in specialized polymerizations to control molecular weight and properties.
Safety & Risks

Classified as Flammable, Corrosive, and Toxic. Releases highly toxic Methyl Mercaptan Gas upon contact with acids; handle with Self-Contained Breathing Apparatus (SCBA) and Acid-Resistant PPE.

Packaging

200 kg Steel Drums, 1000 kg IBC Tanks, and specialized Isotanks for bulk transport.