Sodium Hydrosulfite

ALTERNATIVE NAMES

Sodium Sulfhydrate

TECHNICAL SPECIFICATIONS
CAS
16721-80-5
EC
240-778-0

Sodium hydrosulfite, also known as sodium dithionite or sodium hypodisulfite, is a white to grayish crystalline powder with formula Na2S2O4 and molecular weight 174.11 g/mol. It has a density of 2.38 g/cm³, decomposes above 90°C, and emits a faint sulfurous odor. Highly soluble in water (up to 182 g/L at 20°C) but insoluble in alcohols; unstable in air, oxidizing to sodium bisulfate. Acts as a powerful reducing agent, produced from zinc and SO2 or formate reduction.

Sodium Hydrosulfite

Key in textile dyeing for reducing vat dyes like indigo; in paper bleaching for pulp whitening; water treatment for deoxygenation; organic synthesis, photography, and as a quencher in biochemistry.

Spontaneously combustible in moist air; reacts with water or acids to release toxic SO2. Irritates skin, eyes, and respiratory system. Store dry and cool; UN1384, Hazard Class 4.2; use PPE.

In 50kg iron or fiber drums with PE liners to exclude moisture. Handle carefully to prevent ignition from friction.

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